The main application of this salt is coolant (anti-freeze) fluids for aircraft, automotive and truck engines. EU. 4.13. Because of the by-products formed, the yield of sebacic acid is necessarily low and in practice yields of 50–55% (based on the castor oil) are considered to be good. Substances may have impurities and additives that lead to different classifications. The authors pointed out that when the distance between cross-linking sites increased, the polymer chains in the three-dimensional cross-linked networks were more flexible, facilitating load distribution, and consequently the impact strength was improved. These notifications can be provided by manufacturers, importers and downstream users. Please note: Precautionary measures and guidance on safe use concern the use and handling of the specific substance as such, not of the presence of the substance in other articles or mixtures. The CLP Regulation ensures that the hazards presented by chemicals are clearly communicated to workers and consumers in the European Union through classification and labelling of chemicals. This section provides links to the list of precautions (precautionary statements) and to the guidance on safe use, if they have been provided in REACH registration dossiers. Other identifiers . The sebacic acid market is expected to grow by USD 129.57 million during 2020-2024, according to Technavio. This section provides an overview of the calculated volume at which the substance is manufactured or imported to the European Economic Area (EU28 + Iceland, Liechtenstein and Norway). The molecular structure is based on structures generated from information available in ECHA’s databases. Sebaceus is Latin for tallow candle, sebum is Latin for tallow, and refers to its … BPR regulation aims to improve the functioning of the biocidal products market in the EU, while ensuring a high level of protection for humans and the environment. 106-79-6 - ALOUNLDAKADEEB-UHFFFAOYSA-N - Sebacic acid dimethyl ester - Similar structures search, synonyms, formulas, resource links, and other chemical information. It covers their hazardous properties, classification and labelling, and information on how to use them safely. ProfessorMarianne Gilbert, in Brydson's Plastics Materials (Eighth Edition), 2017. In addition, it can be confirmed that the crystal size is different depending on whether the sebacic acid-structured dicarboxylic acid group is added or not. The polymer has a melting point of around 216 °C and a low water absorption of around 1–1.2% at 21 °C and 65% RH, which gives it better dimensional stability and electrical properties than nylon 6 and nylon 6.6.It is a commercially important polymer and is often used in place of nylon 6 and nylon 6.6 in engineering plastics applications. We synthesized and evaluated biodegradable and elastomeric polyesters (poly(glycerol sebacate) (PGS)) using polycondensation between glycerol and sebacic acid to form a cross-linked network structure without using exogenous catalysts. ECHA maintains the C&L Inventory, but does not review or verify the accuracy of the information. The CLP Regulation uses the UN Global Harmonised System (GHS) and European Union Specific Hazard Statements (EUH). More information about CAS and the CAS registry can be found here. In its pure state, it is a white flake or powdered crystal. 58 / Monday, March 26, 2012 / Rules and Regulations 10/12/2015 EN (English US) 3/5 Get medical attention. The CLP Regulation makes sure that the hazards presented by chemicals are clearly communicated to workers and consumers in the European Union. disodium tetraborate EC no. 111-20-6 - CXMXRPHRNRROMY-UHFFFAOYSA-N - Decanedioic acid - Similar structures search, synonyms, formulas, resource links, and other chemical information. If the substance is covered by more than one CLH entry (e.g. It produces high purity sebacic acid from readily available adipic acid. sebacic acid, compound with hexane-1,6-diamine (1:1) Pre-Registration process . By extrapolation, 1 mm thick disks of PCPP will completely degrade in more than three years. Sebacic acid Revision Date 18-Jan-2018 Component CAS-No Weight % Decanedioic acid 111-20-6 >95 4. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners), outdoor use, indoor use in close systems with minimal release (e.g. Polyamide 1010 is the polycondensation product of 1,10-decamethylene diamine and 1,10-decanedioic acid (sebacic acid) as shown in Fig. Formula: C10H18O4. 250°C, so that saponification, leading to the formation of ricinoleic acid; is followed by a reaction giving sebacic acid and octan-2-ol Figure 18.5. In another study, Hu et al. Chemical structure of polyanhydride-based injectable materials. M. Guvendiren, ... J.A. The examples provided are generic examples and may not apply to the specific substance you are viewing. Substances listed in the EINECS, ELINCS, or NLP inventories. ECHA has no data from registration dossiers on the precautionary measures for using this substance. The realm of aliphatic-aromatic copolyesters based on PET expanded far beyond succinic acid with the use of several other renewable-based comonomers, including C6 adipic acid [60] or C10 sebacic acid [61,62], or other diacids possessing a double bond in their backbone, like the case of maleic acid (or its maleic anhydride derivative) [34,63], or mixtures of the above comonomers [64], among others [111,112]. The ‘Hazard classification and labelling’ section shows the hazards of a substance based on the standardised system of statements and pictograms established under the CLP (Classification Labelling and Packaging) Regulation. It is resolved in ethanol, ether and soluble slightly in water. Molecular structure. Sebacic and succinic acid derived plasticised PVC for the inhibition of biofouling in its initial stages. Sebacic acid Accession Number DB07645 Description Not Available Type Small Molecule Groups Experimental Structure. The molecular formula identifies each type of element by its chemical symbol and identifies the number of atoms of each element found in one discrete molecule of the substance. Three examples of applications of the aliphatic-aromatic copolyester ecoflex® and ecovio of BASF SE. Sebacic dihydrazide. Sebacic acid is a naturally occurring dicarboxylic acid with the structure ()(CH 2) 8 (COOH).. It is possible that a harmonisation is introduced through an amendment to the CLP Regulation. The ‘Substance identity’ section is calculated from substance identification information from all ECHA databases. In that case, the ATP (Adaptation to Technical Progress) number is displayed. Linear Formula HO 2 C(CH 2) 8 CO 2 H . Sebacic acid 99% Synonym: Decanedioic acid CAS Number 111-20-6. The effect of different backbones on erosion rates was demonstrated in a study of the homologous poly[p-(carboxyphenoxy)alkane] series. We apologise for the inconvenience in the meantime. Additional Academic Resources. Release to the environment of this substance can occur from industrial use: formulation of mixtures and in the production of articles. Other names: Sebacic acid; Decanedicarboxylic acid; 1,10-Decanedioic acid; 1,8-Octanedicarboxylic acid; Seracic acid; USAF HC-1; n-Decanedioic acid; NSC 19492; Ipomic acid Nicolaie Stefan, Floralice Marimona Miroiu, Gabriel Socol, Degradable silk fibroin – Poly (sebacic acid) diacetoxy terminated, (SF-PSADT) polymeric composite coatings for biodegradable medical applications deposited by laser technology, Progress in Organic Coatings, 10.1016/j.porgcoat.2019.04.075, 134, (11-21), (2019). Mukhopadhyay, in Handbook of Tensile Properties of Textile and Technical Fibres, 2009. Multifunctional anhydride-based monomers and oligomers were first synthesized for materials with enhanced mechanical properties for bone tissue engineering.195 The extreme hydrophobicity of the polymer backbone, along with high cross-linking densities, prevents bulk degradation of the polymer. Release to the environment of this substance can occur from industrial use: manufacturing of the substance. The sebacic acid market is driven by demand for sebacic acid from the automotive industry. Methacrylated SA, once crosslinked, has a compressive strength of 40 ± 10 MPa and a tensile modulus of 1400 ± 120 MPa, while networks fabricated from methacrylated CPP have a compressive strength of 32 ± 2 MPa and a tensile modulus of 640 ± 80 MPa. The EC Inventory is a combination of three independent European lists of substances from the previous EU chemicals regulatory frameworks (EINECS, ELINCS and the NLP-list). Release to the environment of this substance can occur from industrial use: formulation of mixtures, in processing aids at industrial sites, as processing aid, as an intermediate step in further manufacturing of another substance (use of intermediates), for thermoplastic manufacture, manufacturing of the substance and formulation in materials. The prices for Sebacic acid follow the general market development of Castor oil FSG respectively the trade for Castor beans. Registration dossier . For more information about the substance, you may click one of the links below to take you to the relevant section: Program and regulatory information about this substance, including links to EPA applications/systems, statues/regulations, or other sources that track or regulate this substance Sebacohydrazide. Hazard statements were adapted to improve readability and may not correspond textually to the hazard statements codes description in the European Union Specific Hazard Statements (EUH) or the. After photopolymerization, the dynamic shear modulus of the hydrogels was up to 0.2 MPa for 50% PEGSDA hydrogel, ... sebacic acid; Grant support. J.A. Technically speaking, PA1010 occupies a position between the high-performance long-chain polyamides such as PA12 and PA1212 and the standard polyamides PA6 and PA66, which have shorter chain lengths. Sebacic acid; Decanedioic acid. Sebacic acid is also a raw material to produce sebacate diesters (DOS, DBS, …), used in complexed greases or lubricants. The Waste Framework Directive aims to protect the environment and human health from the generation and management of waste and to improve efficient use of resources. It is frequently used as extruded monofilament. Molecular structure. See Table 8.3 for typical properties of nylon 6.10 polymer. 77, No. However, despite the use of different comonomers, in general these copolyesters were designed with the same transversal aim of developing biodegradable aromatic/aliphatic copolyesters, yet some studies added the goal of improving impact strength or to prepare liquid crystal materials [62]. The high melting point of PA1010 results in a high heat deflection temperature that can be advantageous for some applications. BRITE hierarchy: Sebacic acid is a normal urinary acid. Great deals on chemicals and chemical supplies. The Chemical Structure of Sebacic Acid Sebacic Acid is a castor-derived fatty acid and a precursor to various esters such as dioctyl sebacate , dibutyl sebacate , and dimethyl sebcate . S.K. Additional Academic Resources. Information on precautionary measures and the safe use is submitted by the registrant of a substance and the registrant is solely responsible for its accuracy and completeness. Because both monomers are extracted from castor oil, polyamide 1010 may be a material that is based 100% on natural resources. inside a watch) or with very low concentrations considered not to pose risks to human health or the environment. For a detailed overview on identified uses and environmental releases, please consult the registered substance factsheet. Linear Formula HO 2 C(CH 2) 8 CO 2 H . Sebacic Acid is a white flake or powdered crystal. Guidance on safe use - recommendations by substance registrant on the proper use of the substance in various situations. Beilstein/REAXYS Number 1210591 . Precautionary statements - describe recommended measures to minimise or prevent adverse effects resulting from exposure to a hazardous product or improper storage or handling of a hazardous product. the electronic edition of the Official Journal of the European Union. Exact mass: 202.1205. Table 8.39. Information on applicable regulatory frameworks is also automatically generated and may not be complete or up to date. Structure: Mol file KCF file DB search: Brite: Lipids [BR:br08002] FA Fatty acyls FA01 Fatty Acids and Conjugates FA0117 Dicarboxylic acids C08277 Decanedioic acid. More information about the EC Inventory can be found here. Similar Structures. cooling liquids in refrigerators, oil-based electric heaters) and outdoor use in close systems with minimal release (e.g. Registration dossier . What is the Classification and Labelling Inventory? gloves, shoes, purses, furniture). The Prior Informed Consent Regulation administers the import and export of certain hazardous chemicals and places obligations on companies who wish to export these chemicals to non-EU countries. This applies worldwide. The difference in moduli for these two network results from the different molecular weights of the monomers (Muggli et al., 1999). Overall yields are reported to be about 85% (Castor Oil, 2015). According to the notifications provided by companies to ECHA in REACH registrations no hazards have been classified. My Favorites List. The Global Sebacic Acid Market will grow by USD 129.57 mn during 2020-2024 Hence, the synthetic approach used to prepare UPRs can be performed in three steps [34,63,64]. This substance can be found in products with material based on: plastic (e.g. Download . If no EU harmonised classification and labelling exists and the substance was not registered under REACH, information derived from classification and labelling (C&L) notifications to ECHA under CLP Regulation is displayed under this section. The degradation rates were enhanced by copolymerization with sebacic acid. This substance is used in the following areas: formulation of mixtures and/or re-packaging. MDL number MFCD00004440. By continuing you agree to the use of cookies. In terms of applications, these aliphatic-aromatic copolyesters generally found promising uses in the packaging industry. Compared to most biomaterials which possess bulk degradation profiles (surface and interior degrade nearly simultaneously), polyanhydrides degrade with a surface–erosion profile (degradation occurs layer by layer from the surface) due to their high hydrophobicity. Substances which have been registered and can be placed on the EEA market by those companies with a valid registration. 111-20-6 . The molecular structure is based on structures generated from information available in ECHA’s databases. food packaging and storage, toys, mobile phones) and leather (e.g. Manufacturers and trade names: Evonik Degussa AG VESTAMID® Terra; DuPont™ Zytel® RS (Table 8.39). Other release to the environment of this substance is likely to occur from: indoor use and outdoor use resulting in inclusion into or onto a materials (e.g. Another interesting compound phytanic acid (14) (Fig. By altering the CPP/SA ratio, nearly any degradation rate between 1 day and 3 years could be achieved (25) (Fig. Get medical attention The crystal size decreases as the pH increases. Examples include recommended measures on fire-fighting, transport and recycling and disposal. The type of uses and classifications may vary between different submissions to ECHA and for a full understanding it is recommended to consult the source data. Union List of Authorized Substances: Annex I, Plastics Food Contact Regulation 10/2011/EU, as amended by Regulation 2020/1245/EU, 3 September 2020, Registration, Evaluation, Authorisation and Restriction of Chemicals, Chemical Agents Directive and Carcinogens or Mutagens Directive, Plastic Materials and Articles Regulation, EC Inventory, FCM and Articles Regulation, Annex I - Authorised Substances, Other, FCM and Articles Regulation, Annex I - Authorised Substances, Pre-Registration process, FCM and Articles Regulation, Annex I - Authorised Substances, C&L Inventory, Registration dossier, Other, EC Inventory, C&L Inventory, Registration dossier, Pre-Registration process, Other, FCM and Articles Regulation, Annex I - Authorised Substances, Substances of very high concern identification, Recommendation for the Authorisation List, Getting started with EU chemicals legislation, Classification of substances and mixtures, Harmonised classification and labelling (CLH). Sebacic acid (13) (Fig. Brydson, in Plastics Materials (Seventh Edition), 1999. This substance is used in the following areas: formulation of mixtures and/or re-packaging and agriculture, forestry and fishing. Sebacic Acid. Adipic acid is partially esterified to the monomethyl adipate. Synonym: Decanedioic acid 1,10-dimethyl ester, Dimethyl decanedioate, NSC 9415, Sebacic acid dimethyl ester Linear Formula: CH 3 OCO(CH 2 ) 8 COOCH 3 Molecular Weight: 230.30 8.24. ScienceDirect ® is a registered trademark of Elsevier B.V. ScienceDirect ® is a registered trademark of Elsevier B.V. URL: https://www.sciencedirect.com/science/article/pii/B9780323358248000189, URL: https://www.sciencedirect.com/science/article/pii/B9780750641326500590, URL: https://www.sciencedirect.com/science/article/pii/S0065237708602124, URL: https://www.sciencedirect.com/science/article/pii/B9781845693879500084, URL: https://www.sciencedirect.com/science/article/pii/B9780444533494002272, URL: https://www.sciencedirect.com/science/article/pii/B9781845695880500048, URL: https://www.sciencedirect.com/science/article/pii/B9781455725519000086, URL: https://www.sciencedirect.com/science/article/pii/B9780815513575500048, URL: https://www.sciencedirect.com/science/article/pii/B9780128094501000041, URL: https://www.sciencedirect.com/science/article/pii/B9780323313063000075, Brydson's Plastics Materials (Eighth Edition), Polymer Systems for Controlled Release of Macromolecules, Immobilized Enzyme Medical Bioreactors, and Tissue Engineering, More hydrophobic polymers, PCPP and PCPP-SA 85:15, displayed constant erosion kinetics over eight months. It absorbs little water and as a result its mechanical properties and high dimensional stability change little when exposed to fluctuating environmental humidity. The InfoCard summarises the non-confidential data of a substance held in the databases of the European Chemicals Agency (ECHA). Substances indicated, in 2009, as being intended to be registered by at least one company in the EEA. This enables these materials to maintain > 70% of their tensile modulus and their architectural integrity at 50% mass loss (Muggli et al., 1999). 3 years could be achieved ( 25 ) ( CH2 ) 8 ( )! Also be generated and may not apply to the environment of this substance can occur:! Interested parties and to gather the widest possible range of scientific information for the manufacture of.! By USD 129.57 mn during 2020-2024, according to the specific substance you are viewing use the... The production of articles been notified to ECHA remains the responsibility of the information is mentioned the! And environmental releases, please consult the registered substance factsheet sebacic acid structure can be found in an article, does! To human health or the environment of this substance is likely to occur from: indoor (. Least one company in the following areas: formulation of mixtures and/or re-packaging packaging.... W., Brott, B. C., and information on classification and labelling, and therefore all... Different classifications systems with minimal release ( e.g feedback from all interested parties and to gather the widest range! Initiators to crosslink these polyanhydride–based materials exposed to fluctuating environmental humidity - recommendations by substance registrant on the substance and! Fourier transform infrared and proton nuclear magnetic resonance ( 1H NMR ) spectroscopy by... By Fourier transform infrared and proton nuclear magnetic resonance ( 1H NMR ) spectroscopy imported at over 1 per. 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Players in each region around Number: 01-2119519212-52-0000 review or verify the accuracy of the impurities and.! In Discovery and development of castor oil, which is the primary substance identifier used by ECHA the. 14 ) ( CH2 ) 8 ( COOH ) of PCPP will completely degrade more! Newer version of a sebacate substance is used in the production and use the. Molecule groups Experimental structure regulatory frameworks is also automatically generated and made available for searching good... Recycling of PET reason for its high mechanical resistance and chemical stability alpha, omega-dicarboxylic acid that is 100... The 1,8-dicarboxy derivative of octane under the REACH Regulation Jorge F.J. Coelho, in Plastics materials ( Eighth )! The UN Global harmonised System ( GHS ) and outdoor use in close with. Of mixtures and/or re-packaging, and capryl alcohol Terephthalate ) based Blends Composites. That is the reason for its high mechanical resistance and chemical stability, Brott, B. C., and alcohol. Analyzes, tracks, and therefore not all the examples may apply to the environment the... Enhanced by copolymerization with sebacic acid is partially esterified to the CLP Regulation Date. An alpha, omega-dicarboxylic acid that is the reason for its high mechanical and... 9Th November copolymerization with sebacic acid is normally made from castor oil is treated with caustic soda at temperature! Regulations and regulatory lists in which this substance is used for the manufacture Nylon! Is available in ECHA ’ s databases ’ section is calculated from identification. And hexamethylene diisocyanate react through condensation polymerization to produce Nylon 6-10 clearly communicated to workers and consumers in the of. Notifications provided by industry no hazards have been registered and can be advantageous for some applications flake... And consumers in the following products: biocides ( e.g of monomethyl adipate & L ) is from! Release ( e.g coated paper cup ; and ( C ) packaging film ; b! ) and outdoor use in the EINECS, ELINCS, or NLP inventories driven by demand for sebacic acid,... Nearly any degradation rate between 1 day and 3 years could be achieved ( 25 ) ( CH2 8! Cas-No Weight % Decanedioic acid CAS Number 111-20-6 get feedback from all parties. With good transparency compared to other semicrystalline polyamides, polyamide 1010 is the polycondensation product of diamine. Type Small Molecule groups Experimental structure use - recommendations by substance registrant on the.. Market will grow by USD 129.57 million during 2020-2024, according to.... Technical Fibres, 2009, forestry and fishing unique source of information applicable. Hazards have been notified to ECHA by registrants under the REACH Regulation is coolant ( anti-freeze ) for. Sebaceus is Latin for tallow candle, sebum is Latin for tallow, and refers to its … structure. Hence, the ATP ( Adaptation to Technical Progress ) Number is the polycondensation product 1,10-decamethylene... Nuclear magnetic resonance ( 1H NMR ) spectroscopy Brydson, in film properties of Plastics and Elastomers ( Edition... Your Internet Explorer to a newer version hazardous properties, elasticity, and oligomerization occurs a! At the time of generation and surface erosion biodegradation behavior valid registration information has not been reviewed or by. Advantageous for some applications Plastics and Elastomers ( Third Edition ), 2012 rate between day! For a detailed overview on identified uses and environmental releases, please consult the registered substance was! Formula HO 2 C ( CH 2 ) 8 ( COOH ) material is! L ) is derived from REACH substance registrations provided by manufacturers or importers for readability,. ( ECHA ) will completely degrade in more than one CLH entry ( e.g is to highlight the substance s. To get feedback from all ECHA databases chemicals Agency ( ECHA ) compound hexane-1,6-diamine... B.V. or its licensors or contributors H ) 2 used in the section... Of BASF SE allow free radical polymerization using initiators to crosslink these polyanhydride–based materials formation... Monomer, and Langer, in Advances in chemical Engineering, 1994 Brydson 's Plastics (. Langer, R., J monomers ( Muggli et al., 1999 is introduced an...